Round 5: Tossup 2

Linkages named for this functional group join the monomers of the 3D printing filament PLA. Compounds with this functional group and acyl (“ace-ill”) chlorides react with [emphasize] two equivalents of Grignard reagent to form tertiary alcohols. Cyclic varieties of these compounds are known as lactones. Examples of these compounds (10[1])such as triglycerides (-5[1])can be hydrolysed with sodium hydroxide in saponification. Names of these compounds feature the suffix “-oate,” (“oh-ate”) as in methyl propanoate (-5[1])(“pro-PAN-oh-ate”). In a reaction named for Emil Fischer, these compounds are synthesized by refluxing an alcohol with a carboxylic acid. (10[1])For 10 points, an R-C-O-O-R’(“R-C-O-O-R-prime”) group (10[1]-5[1])characterizes what fruit-scented compounds? ■END■

ANSWER: esters [accept Fischer esterification; accept ester linkages; prompt on lactones until read]
<Editors, Chemistry> | Packet E
= Average correct buzzpoint

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Buzzes


Summary

TournamentEditionMatchHeardConv. %Neg %Avg. Buzz
Northern CaliforniaMain450%100%89.50
Southern CaliforniaMain786%29%61.33
Eastern Canada (1)Main5100%0%57.40
Eastern Canada (2)Main978%67%84.00
FloridaMain425%75%99.00
Great LakesMain1182%45%73.22
Lower Mid-AtlanticMain875%25%59.67
Upper Mid-AtlanticMain1100%100%99.00
Upper Mid-AtlanticMain956%67%77.40
Upper Mid-AtlanticMain250%50%99.00
MidwestMain978%78%95.57
NorthMain450%0%91.50
NortheastMain1100%0%80.00
PacificMain875%25%72.17
South CentralMain580%40%72.75
SoutheastMain1060%70%81.17
Upstate NYMain560%20%84.33
UK (North)UK580%60%81.50
UK (South)UK8100%50%75.75