Round 1: Tossup 17

Iodine and this ligand are complexed with iridium to catalyze the production of acetic acid from methanol in the Cativa process. (10[1])Due to pi-backbonding, this ligand has the largest crystal-field splitting parameter in the spectrochemical series. This compound and hydrogen form water gas, (-5[1])and it is the primary reducing (10[1])agent in blast furnaces. Though it is not produced during complete combustion, (10[1])incomplete combustion (10[1])produces this compound. (10[2])This compound binds 200 times more strongly to hemoglobin than oxygen, (10[1]-5[1])so low concentrations can lead to poisoning. For 10 points, name this odorless (10[1])and colorless gas (10[2])with formula CO. ■END■ (10[2])

ANSWER: carbon monoxide [accept CO until read; accept carbon monoxide poisoning; accept carbonyl ligand]
<Notre Dame A, Chemistry> | Packet B
= Average correct buzz position

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